Structural and electrochemical properties of amorphous rich MgxNi100-x nanomaterial obtained by mechanical alloying
Identifieur interne : 000283 ( France/Analysis ); précédent : 000282; suivant : 000284Structural and electrochemical properties of amorphous rich MgxNi100-x nanomaterial obtained by mechanical alloying
Auteurs : M. Abdellaoui [Tunisie] ; S. Mokbli [Tunisie] ; F. Cuevas [France] ; M. Latroche [France] ; A. Percheron-Guegan [France] ; H. Zarrouk [Tunisie]Source :
- Journal of alloys and compounds [ 0925-8388 ] ; 2003.
Descripteurs français
- Pascal (Inist)
English descriptors
- KwdEn :
Abstract
Using a planetary ball mill and starting from a mixture of Mg2Ni and Ni with a Mg atomic content ranging from 40 to 60 at.%, we have elaborated amorphous phase alloys with little quantities of residual Ni. The synthesis of the amorphous phase proceeded at 6.49 W g-1 shock power, for milling durations ranging from 8 to 10 h for Mg40Ni60 and Mg60Ni40 samples, respectively. The best electrochemical capacity (470 mAh g-1, equivalent of MgNiH2.0) was obtained for the Mg50Ni50 sample synthesized in milling duration 10 times shorter than that commonly reported in the literature.
Affiliations:
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Pascal:03-0428843Le document en format XML
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<term>Hydrogen storage</term>
<term>Magnesium alloys</term>
<term>Mechanical alloying</term>
<term>Nanostructured materials</term>
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<term>Nanostructure</term>
<term>Magnésium alliage</term>
<term>Alliage binaire</term>
<term>Alliage MgNi</term>
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<front><div type="abstract" xml:lang="en">Using a planetary ball mill and starting from a mixture of Mg<sub>2</sub>
Ni and Ni with a Mg atomic content ranging from 40 to 60 at.%, we have elaborated amorphous phase alloys with little quantities of residual Ni. The synthesis of the amorphous phase proceeded at 6.49 W g<sup>-1</sup>
shock power, for milling durations ranging from 8 to 10 h for Mg<sub>40</sub>
Ni<sub>60</sub>
and Mg<sub>60</sub>
Ni<sub>40</sub>
samples, respectively. The best electrochemical capacity (470 mAh g<sup>-1</sup>
, equivalent of MgNiH<sub>2.0</sub>
) was obtained for the Mg<sub>50</sub>
Ni<sub>50</sub>
sample synthesized in milling duration 10 times shorter than that commonly reported in the literature.</div>
</front>
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